If you are planning to use QuickBooks module, set QuickBooks options after enabling QuickBooks in the Modules section of the admin interface.
Click on General settings in the Administration menu, select QuickBooks options from the section menu.
Set the options below according to your preferences:
Picture 1: QuickBooks options.

Click on Save to save the changes.
Note. To change the default accounts and other information specific for QuickBooks, edit the template skin1/modules/QuickBooks/orders_export_qb.tpl
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